Yes — based on the RA6E1 LQFP-64 datasheet, I’d group each physical pin only once by its primary/common function like this:
Power / Supply
- VCC: pins 10, 19, 57
- VCC_USB: pin 44
- VBATT: pin 3
Ground
- VSS: pins 7, 20, 56
- VSS_USB: pin 47
Internal Regulator / Stabilization
Analog Supply / References
- AVCC0: pin 24
- AVSS0: pin 25
- VREFH: pin 23
- VREFL: pin 32
- VREFH0: pin 27
- VREFL0: pin 26
Clock
- XCIN: pin 5
- XCOUT: pin 6
- P213 / XTAL: pin 8
- P212 / EXTAL: pin 9
Reset / Boot Mode
- RES: pin 39
- P201 / MD: pin 38
USB
- USB_DP: pin 45
- USB_DM: pin 46
Debug / SWD / JTAG
- P300 / TCK / SWCLK: pin 33
- P108 / TMS / SWDIO: pin 64
- P110 / TDI: pin 61
- P109 / TDO / SWO: pin 63
GPIO / Multifunction I/O
- P400: pin 1
- P402: pin 2
- P411: pin 11
- P401: pin 12
- P410: pin 13
- P409: pin 14
- P408: pin 15
- P407: pin 16
- P000: pin 17
- P500: pin 18
- P015: pin 21
- P014: pin 22
- P004: pin 28
- P003: pin 29
- P002: pin 30
- P001: pin 31
- P301: pin 34
- P302: pin 35
- P303: pin 36
- P304: pin 37
- P208: pin 40
- P205: pin 41
- P206: pin 42
- P207: pin 43
- P200: pin 48
- P100: pin 49
- P102: pin 50
- P103: pin 51
- P104: pin 52
- P105: pin 53
- P106: pin 54
- P113: pin 58
- P112: pin 59
- P111: pin 60
- P101: pin 62
No pin is duplicated between groups. For pins with alternate functions, I placed them in the most common/primary group: power pins in power, oscillator pins in clock, USB data pins in USB, SWD/JTAG-capable pins in debug, and the remaining multifunction port pins in GPIO.