Great—USB-charged 2‑cell (2S) Li‑Ion with USB as primary is a perfect fit for a buck‑boost charger with NVDC/power‑path, so your system runs from USB when present and falls back to battery seamlessly.
Proven charger ICs (all support 2S, NVDC power path, and buck‑boost from 5 V per datasheets)
BQ25713RSNR — 1–4S, NVDC power path, 3.5–24 V input, seamless buck/buck‑boost/boost. Per datasheet: “Charge 1s to 4s… 3.5 V to 24 V… Seamless transition among buck, buck‑boost and boost operations” and “Narrow voltage DC (NVDC) power path management.”
BQ25792RQMR — 1–4S NVDC buck‑boost, Vin 3.6–24 V, I2C, adapter detection. Datasheet calls out NVDC power path and wide input (3.6–24 V).
MP2762A — dedicated 2S NVDC buck‑boost charger, 4–21 V input. Datasheet: “for 2 cells in series,” NVDC power path, boost charging when Vin 5 V): add a PD sink controller such as STUSB4500QTR or TPS25750DRJKR to request 9–12 V for higher efficiency. Design power stages to support negotiated voltages.
Got it: USB-C with PD at 9 V, and a 2S Li‑Ion charger. Below are clean, simple pairings that make USB the primary source and seamlessly charge/run the system. Per best practice, size your power stages to the negotiated PD voltage/current you plan to request (e.g., 9 V), and consider headroom if you may later allow 12 V.
USB-C PD sink (standalone, fixed 9 V capable)
STUSB4500QTR - Standalone PD sink, widely used for fixed PDOs with NVM profiles.
CYPD3177-24LQXQ - Standalone PD sink, very simple bring-up for power-only sinks.