In the current schematic, C5 is a 100 nF capacitor connected directly from U3VDD to GND, and its role is already tagged as “Decoupling for HDC3020 VDD pin.”
That matches standard local bypass practice for IC supplies: 100 nF MLCC is the normal value for a local decoupling capacitor
Updated list treatment
Move C5 out of the vague “sensor power and decoupling” bucket and call it out explicitly as:
Sensor local decoupling
C5 — 100 nF local bypass capacitor for U3, connected from VDD to GND
Keep it physically close to U3, since decoupling caps should stay near the IC they support; supporting components should move with their IC during placement